I agree with most of it as well as the DazedMadonna corrections. However;
(Blond Ambition Tour)
Express Yourself (Selected dates live, others lip synced)
(MDNA Tour)
Papa don't preach (verse and chorus sung live EXCEPT for the pre-chorus, AKA 'the one you warned me)
I'm Addicted (First Verse sung live and then rest is lip synced) (The clue is in the breathy sound of the bridge when she says 'I don't care if you...')
(Rebel Heart Tour)
Gypsy Medley (Sung live EXCEPT for into the groove as it always sounds the same and slightly autotuned compared to the rest of the medley!)
Living for love (lip synced for most of the tour but around February Madonna started singing it live)
Bitch I'm Madonna (Sung live for the first few shows then partially lipped till about end of November then fully lip synced after that)